Old182
Senior Member
Virtually all gasolines contain butanes and pentanes for front end volatility (easy vaporization for startup). Butane boils at 31*F - maybe that's what we see bubbling in fuel lines and filters when underhood temps reach >200*F? And maybe that's what we see coming out of gas tanks when we remove the cap on a hot day? Gasolines begin boilng at ~70-80*F and finish no higher than 437*F. Ethanol boils at 172*F. One might think a lot of "gasoline" would have to boil off before the ethanol boiled (even considering the mixing). Check the attached distillation curve courtesy SAE Fuels Handbook. It shows the effect of ethanol and other "crappy" stuff on the boiling characteristics of a "normal" gasoline compared to "crap gas" (thanks, Tom). The depression caused by 10% ethanol generally causes hard starts on cold days, but doesn't do much (if any) harm to performance once warmed up. However, the low Reid vapor pressure of ethanol (2.3 psi) can contribute somewhat to vapor locking and the boiling point of ethanol lowers the temperature at which the vapor to liquid ratio is 20:1 (known as T20 V/L). That temperature has been found to be the best predictor of vapor lock. As several have already pointed out, you might get boiling, bubbling, hissing, percolation or whatever in your iron carburetor or fuel line, but it's doubtful vapor lock - even with the crap gas we're all dealing with. Besides, in a few years it'll be in all gasoline sold in the U.S., big city or not; better get used to it.