The piston will pull out, just very hard. Nothing holds it in the can.
Obviously you need to remove the vacuum input tube and the vent screen. Make sure there are no bures on the inside from the screws and the piston is square in the can. Take off the master cover and the big screw in valve under it and you will be able to see the push rod, might be able to pry on the front edge of it to get things started. If it is all goobered up it will help hold the piston in. Blowing air in the master will not help, the push rod is well sealed from the vacuum side of things.
After the piston is out you will see the push rod and a squarish looking plate. Push down on the plate and a "C" clip will come out. Just remove the C clip, plate and large spring. Three bolts hold the master to the can.
When putting the assembly back together the large valve inside the master is the last part to be put in. This is after every other part is back in place. Push the vacuum piston all the way in, screw the valve in place, put the cover back on and re intsall the assembly before you pull the vacuum piston back out. Pull it out just enough to engae the pedal with the pedal down, put the bolt in, and pull it back out with the pedal.