now i get it, the hex broke free of the rest of the threads and rode up the porcelain.
Threads must really be rusted up, never saw this one before!
Might have to use a die grinder with a cylindrical bit to cut into the shell a little bit at 2 locations. One location might be enough. Don't worry about cutting into the head threads, it is the copper washer that does the sealing anyway.
Set that cyl. so the intake valve is open, and use a freshly cleaned (thus more powerful) vacuum to suck up the grindings at the same time you are grinding.
Then use a small punch or screwdriver between the shell and the head and a small hammer and gently pry the shell free. Once it starts to free up it will go much easier.
You will need to chase the threads if that rusted, again use the vacuum cleaner trick at the same time...do a little at a time