I did a search and see 3m 5200 is a urethane.
A bead of urethane has been used to hold windshields in cars for the past 30+ yrs. It fills gaps, adheres to smooth, carefully prepared surfaces & cures to a rubber tire consistancy.
I can see it being used to seal top moldings successfully, although anyone who's never handled the product is in for a surprise in the cleanup department as it's relatively fast curing, very messy and tends to "get away" from you.
Assuming we're taking advantage of a sunny day to smooth out the roof material wrinkles, I'd say the urethene will begin setting up in 10 minutes ...that's the workable stage...after this it still moves around except with each move you're permanently breaking the bond and increasing the risk of water seepage. I've worked with alot of urethane and not sure I'd want to be rushed like this on something as finicky as a top, although if you were an expert it would be one heck of a strong bond providing one could get it all nailed down in time!
My feelings are that I would still prefer the selfhealing, reflowable properties of a butyl product under my roof moldings as it's far less permanent and infinately reworkable over extended time periods.
Many of you folks have more experience with Model A tops than me... I remain open to all feedback.