Old one was painted with crappy paint and crappy prep. Get all that paint off there with paint stripper, then wire wheel it down to nice clean cast iron. Use phosphoric acid generously with a steel wool pad (plain steel wool, not Brillo which has soap in it) to scrub the phos in deep, wipe off with clean white rag, change rag, repeat until no discoloration comes off on the rag, wipe dry ( do NOT rinse), sun dry or play a propane flame or heat gun over it GENTLY until it is dry. It will turn a nice gray battleship color. Use a scotchbrite pad gently to get off any remaining tiny bits of your rags. The metal is now properly prepared for painting in the best known manner. Use a good quality engine green enamel from one of the suppliers like Brattons. You may need 2 coats, NO more. Do not use any primer on the metal, just go straight to the engine green.
I have prepped all my metal parts with this method for about 30 yrs. I did the manifold on my Deluxe more than 20 yrs ago. It still looks like the day I did it. Same for the body of the car....looks like day 1, no rust leaking thru anywhere. And the car was in the humid Northeast for 15 of those years.
There is a thread on here now about using phosphoric acid, search it. This method was documented at least as far back as the '40s, get an old copy of the Metals Handbook and look it up. No restoration or metal work goes out of this shop without this process.