It is not pressurized, as has been stated above. However, the radiator cap should seal. The coolant overflow tube in the top of the radiator, then down the side, is where the coolant should pee out if it is overfull or overheats. FYI, the radiator will not stay full. Add coolant to nearly full then drive for a while. The radiator will find its own level, coolant typically will be just below baffle, but should always stay above the radiator tubes. Typically 50/50 antifreeze is used. If radiator cap leaks put a new seal in it, available from all the parts houses, of more or less quality.