Some of the valves in the picture look pitted at the edges. You need just the 45degree surface as factory but if you don't square the edge up will it make a hot spot?
If you take much meat off the valve will be smaller, & with the original seat ground down it will put the valve seal out toward the edge.
I understand small block chevvie valves can be modified to fit and are a bit bigger, youhave some kicking around I would grab one & compare, there are articles here about that
If you buy new seats at NAPA they are real hard, and there is no angle, used up some stone to get the surface cut as they have a square shoulder.
Whenever i fix up a motor I have I have piston assemblies valves and such to fix and they run a long time. But i look for NOS stuff to use for a overhaul, as far as speedway valves price is cheep and have a set secondhand but I havent used them yet.
I will say as the stock lifters require a stem grind to set gap, I would check the fit with new valves & seats, if the installed assembly has too much gap, maybe reground cam also, may not have adjustment?
Unless you do adjustamle lifters, probably, then no sweat