I've been avoiding responding because I don't have direct model A experience here, but it seems to me that a lot of 2 stroke detonation experience applies, and that I do know about. You definitely had detonation problems. Whether high temp was the cause or effect is always the question.
You can look at better cooling, but no-one has mentioned reducing heat input to the system. Consider some judicious ceramic coating. Ceramics don't really "insulate" as they are too thin, but there is a boundary between the ceramic and the cast iron, similar to a head gasket joint, that provides a real thermal barrier. I'd coat the exhaust ports from the below the valve seats down to the face of the block. Also the top of the block between the valves and the cylinder. Find a good race shop that can mask the area off properly. Consider coating all of the head that faces the flame front. You can coat pistons, but the risk is that any little detonation can blast off ceramic and then there's sand dancing in your cylinders. Use at your own risk.
You can coat the flat face of the valves, as most valve heat transfers through the seat to the block, but that's grabbing at small fry.
Lastly, consider boring into your exhaust ports and inserting a stainless or titanium ring. This is similar to the header ring that is used stock, just deeper. Both ti and stainless have very low heat transfer compared to cast iron and the interface between the ring and the block is another boundary. I haven't done this on an A, so be careful of wall thickness.
None of this helps "cooling", it reduces heat put into the block and head. It can also increase the exhaust temp, so be sure that the header system is robust.
Ceramic isn't super spendy, but the inserts are machine time for sure.
Good luck. Cool project.