The shift it into 2nd thing is a bit of a work around that may be masking a dragging clutch. If you press down the clutch pedal and wait just a few seconds you should be able to engage first or reverse with just the faintest snick as it goes in. If you try to quickly, yes it will clash.
If you press down the pedal and the clutch never really does disengage, it will always clash. Using 2nd first helps overcome this, but does put extra work into the 2nd synchro.
Here's how you test to see if your clutch is releasing or dragging, but it is not for the faint hearted.
With the engine running, move (carefully) the gear lever towards reverse. Don't ram it in, what we are trying to find is the point at which the gears are just touching and making a noise. Use both hands so you have better control. Hold the lever there and start to press down the clutch pedal. At some point the noise will stop. Hold the clutch there and put the lever back in neutral.
Now. this is where you have to make a judgement. You have to gauge how far off the floor your foot is. If you press down and have a good bit of movement before you touch the floor that is good. If you find you have hardly any movement before you hit the floor, that's not so good. What is worse, though, is if you reach the floor before the grating noise stops.
So, the question is, does the noise stop? If so how far off the floor. If it does not stop then it may just be a matter of adjustment.
If it should release, (the adjustment is correct) but it drags, then the lining or centre may be breaking up, or the linings are contaminated with either engine oil or gearbox oil. If the lining or centre breaking up it wouldn't be temperature related (I guess).
The clashing gear technique is a genuine process used in the auto industry (well it was 30 years ago).
If you could do the test (like I said, with care) and report back what you find that would be interesting.
Mart.