Here you go, guys. I know it's a long article, but it will explain a lot of things.
Spark ignition engines are designed to burn gasoline in a controlled process called
deflagration. In some cases, however, the unburned mixture can autoignite (detonate from pressure and heat alone, rather than ignite from the spark plug at exactly the right time), which causes rapid pressure rise which can damage the engine. This phenomenon is often referred to as
engine knocking or end-gas knock. One way to reduce knock in spark ignition engines is to increase the gasoline's resistance to
autoignition, which is expressed by its octane rating.
Octane rating is measured relative to a mixture of
2,2,4-trimethylpentane (an
isomer of
octane) and n-
heptane. There are different conventions for expressing octane ratings, so a fuel may have several different octane ratings based on the measure used. Research octane number (RON) for commercially-available gasoline varies by country. In
Finland,
Sweden, and
Norway, 95 RON is the standard for regular unleaded gasoline and 98 RON is also available as a more expensive option. In the UK, ordinary regular unleaded gasoline is 91 RON (not commonly available), premium unleaded gasoline is always 95 RON, and super unleaded is usually 97-98 RON. However, both Shell and BP produce fuel at 102 RON for cars with high-performance engines, and the supermarket chain
Tesco began in 2006 to sell super unleaded gasoline rated at 99 RON. In the US, octane ratings in unleaded fuels can vary between 86 and 87 AKI (91-92 RON) for regular, through 89-90 AKI (94-95 RON) for mid-grade (European premium), up to 90-94 AKI (95-99 RON) for premium (European super).
The octane rating became important as the military sought higher output for
aircraft engines in the late 1930s and the 1940s. A higher octane rating allows a higher
compression ratio or
supercharger boost, and thus higher temperatures and pressures, which translate to higher power output. Some scientists even predicted that a nation with a good supply of high octane gasoline would have the advantage in air power. In 1943, the
Rolls Royce Merlin aero engine produced 1,320 horsepower (984 kW) using 100 RON fuel from a modest 27 liter displacement. Towards the end of the
second world war, experiments were conducted using 150 RON fuel (100/150 avgas), obtained by adding 2,5% aniline to 100 octane avgas.
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