I had the same problem with #3 intake. I tried spraying kroil in the plug hole, no good. Took the intake off and sprayed into the port directly at the valve and let it sit. no good. I also asked here and everyone said.... pull the head. So I pulled the head and tried to work it out by spraying and tapping gently to free it up. still no good. it would stick everytime I rotated the engine. So, I pulled the valve while it was up and had to use channel lock pliers to rotate and pull that valve. It came out and I could see where the kroil went down the stem, but a tiny piece of carbon was making it stick. I cleaned up the valve and it moved freely in the guide, but I had a nice set of extras from another block,so I lapped one into the cyl and put it all back together and now it runs smooth! Before I did this, she'd pop thru the carb! no more of that.
So, the best advice is to pull the head on the stuck side and take the valve out and clean the stem, and the guide and put it back together. These guys know thier stuff, so heed thier advice and yank the head.
Barry
50 F-1