A couple of notes...
1) If you connect 2 batteries in parallel (for more 6V current capacity), you don't need larger cables leaving the battery. You're circuits won't be drawing more current. You just have more capacity before the batteries die.
2) If you decide to use a 12V at start setup (I wouldn't recommend it unless you go with a full 12V conversion), make sure it routes to the starter only. If you run 12V through your coil, condenser, etc., you will likely burn them up in short order.
3) A note on Optima batteries: I found that Optima 6V batteries tend to have lower RC (Reserve Capacity) values than regular lead acid batteries...not always but frequently. This means you have less total time to crank your engine before the battery can no longer turn the starter motor. Most folks go with the Optima for the storage advantages (no leak, maintenance free, no acid vapors, etc) vs. the old style regular batteries. So...if you've got a hard starting car, the Optima will appear weak (i.e. die quickly) when it's merely a limitation of the design.
Lastly, I concur with the other advice. Don't use 2 batteries in parallel to solve another issue. Check all connections, clean grounds, check battery (sometimes measuring voltage doesn't tell you everything...take the battery to a auto parts store and ask them to do a load check...sometimes batteries short- or open-circuit under heavy loads like starting), check circuits...all good advice.
Best of luck...
COE Dan