DO NOT USE LEAD- FREE SOLDER !!!!
It is mostly tin, and has a significantly higher melting point than lead-alloy solders.
Result: you will wind-up running the old lead solders out of the surrounding joints before you get things hot enough for the lead-free cr__ to melt.
(This goes for repairs to household plumbing too ! )
If you use a propane torch, use a pencil-point burner to concentrate the heat.
The firewall brace-rod brackets are steel, clean them thoroughly and de-grease, then tin the mating surface with the same solder that you will use of the repair.
Clean the area of the tank scrupulously, and tin that as well.
Then, place the tinned bracket on the tank, and apply the flame to the bracket and move it around in a circular motion, hitting the tank about 1/4" beyond the bracket.
You'll see the solder turn shiny-silvery, and see the bracket settle against the tank; adjust the position of the bracket, then remove the heat. Let cool.
(This technique is known as "sweating": the joining of two previously-tinned surfaces)
This is all much easier if the radiator is laying face-down on a bench. If you're concerned about radiant heat affecting other joints, take some old terry cloth ( dish towels), soak, then wring-out so they aren't sopping, then make a "rope" out of the wet towel, and lay that over the nearby joints you want to protect.
Take your time...
Good luck !
(PS: you could use rosin-core, but better to use acid-core or solid 60-40 Lead-Tin and paste flux ( I like Ruby-Fluid ) or liquid acid-flux, both available at plumbing su0pply / better hardware stores. )