I had this problem when I first painted my tank. I found the neck is copper plated down a ways. Someone told me if I masked this copper plated area down to the first ledge and paint only to there it would not peal. I also, once it was dry and before any fuel was put in, I coated this area down to the paint and just over it with clear fingernail polish. Never had a problem in 6 or 7 years.